For citation:
Agoudov N. V., Malakhov A. N. The effect of the shape of the potential profile of the metastable state on its life time temperature dependence. Izvestiya VUZ. Applied Nonlinear Dynamics, 1995, vol. 3, iss. 3, pp. 80-91.
The effect of the shape of the potential profile of the metastable state on its life time temperature dependence
The temperature dependences of the derived exact values of the life times of the metastable states described by some piece-wise linear and piece-wise parabolic potential profiles are investigated. The shape of the potential barrier along with the shape of the other potential profile parts is shown to effect essentially on the metastable state life time τ and on its temperature dependence at any values of the potential barrier height Е. It is demonstrated that well-known Arrhenius low τ = θ0ехр(Е/КТ) (θ0 = const) is correct only for some particular shapes of the potential profile and under small mtensity of fluctuations КТ << Е. It is shown that various deviations of the temperature dependence of the metastable state life times from е Arrhenius low when the prefactor θ0, becomes а function of the temperature, may be explained by the taking into account both the nonparabolic shapes of potential barrier and well and the arbitrary choice of the potential barrier height E in comparison with the fluctuation intensity KT. The various dependences of θ0(KТ) caused by the different specific shapes of the potential wells and barriers under kT << E are given at the end of this paper.
- Risken H. The Fokker - Planck Equation. Methods of Solution and Applications. Berlin: Springer; 1996. 472 p. DOI: 10.1007/978-3-642-61544-3.
- Hanggi P, Talkner Р, Borkovec M. Reaction-rate theory: fifty years after Kramers. Rev. Mod. Phys. 1990;62(2):251-341. DOI: 10.1103/RevModPhys.62.251.
- Anishchenko VS, Neiman AV. Statistical properties of the intermistence effect in quasi-hyperbolic systems. Tech. Phys. 1990;60(1):3-14.
- Tunitskii NN, Kaminskii VA, Timashev SF. Methods of Physical and Chemical Kinetics. М.: Khimiya; 1972. 197 p.
- Kramers НА. Brownian motion in а field of force and the diffusion model of chemical reactions. Physica. 1940;7(4):284-304. DOI: 10.1016/S0031-8914(40)90098-2.
- De Rise George, Adam John А. A generalization of а solvable model in population dynamics. J. Phys. A: Math. Gen. 1990;23(14):L727S-L731S. DOI: 10.1088/0305-4470/23/14/007.
- Frenkel J. Theorie der Adsorption und verwandter Erscheinungen. Z. Phys. 1924;26:117-138. DOI: 10.1007/BF01327320. Frenkel YaI. Kinetic Theory of Liquids. Leningrad: Nauka; 1975. 592 p.
- Evans МС, Polanyi М. Some Applications of the Transition State Method to the Calculation of Reaction Velocities, Especially in Solution. Trans. Far. Soc. 1935;31:875-894. DOI: 10.1039/tf9353100875. Stearn AE, Eyring H. Nonadiabatic Reactions. The Decomposition of N2O. J. Chem. Phys. 1935;3:778-785. DOI: 10.1063/1.1749592. Eyring H, Lin SH, Lin SM. Basic Chemical Kinetics. N.Y.: Wiley; 1980. 493 p.
- Bokshtein BS, Bokshtein SZ, Zhukhovitskii АА. Thermodynamics and Diffusion Kinetics in Solids. М.: Metallurgiya; 1974. 280 p.
- Kohler U, Herzig Ch. On the correlation between self-diffusion and the low-frequency LA 2/3 <111> phonon mode in b.c.c. metals. Phil. Mag. А. 1988;58(5):769-786. DOI: 10.1080/01418618808209952.
- Agudov NV, Malakhov АN. Nonstationary diffusion through arbitrary piecewise-linear potential profile. Exact solution and time characteristics. Radiophys. Quantum Electron. 1993;36(2):97-109. DOI: 10.1007/BF01059491.
- Malakhov АN, Pankratov АL. Temporal diffusion characteristics through an arbitrary piece-parabolic potential profile. Precise solution. Nizhny Novgorod: Nizhny Novgorod State University; 1999. 48 p. Archived in Russian Institute for Scientific and Technical Information 08.08.1994, No. 2057-В94.
- Malakhov АN, Pankratov АL. Times of stochastic transitions in piece-parabolic bistable systems with noise. Izvestiya VUZ. Applied Nonlinear Dynamics. 1995;3(3):70-79.
- Malakhov АN. Cumulant Analysis of Random Non-Gaussian Processes and Their Transformations. М.: Sovetskoe Radio; 1978. 376 p.
- 68 reads