ISSN 0869-6632 (Print)
ISSN 2542-1905 (Online)


For citation:

Usanov D. A., Rebrov V. G., Rytik A. P., Bondarenko A. V. The role of oxygen in Briggs–Rauscher autooscillating reaction. Izvestiya VUZ. Applied Nonlinear Dynamics, 2013, vol. 21, iss. 5, pp. 60-68. DOI: 10.18500/0869-6632-2013-21-5-60-68

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Full text PDF(Ru):
(downloads: 101)
Language: 
Russian
Article type: 
Article
UDC: 
621.373.029.7

The role of oxygen in Briggs–Rauscher autooscillating reaction

Autors: 
Usanov Dmitrij Aleksandrovich, Saratov State University
Rebrov Viktor Georgievich, Saratov State University
Rytik Andrej Petrovich, Saratov State University
Bondarenko Anna Vasilevna, Saratov State University
Abstract: 

It is description of the way in which chemical environment of Briggs–Rauscher autooscillating reaction affects characteristics of oscillations. It has been ascertained that variations of the iodide complexes concentrations perhaps occurs due to increases of oxygen concentration in media and intermediate’s concentration fluctuation. Influence was investigated one of the basic natural oxidizing agent oxygen and it radical forms on autocooperative mechanisms of Briggs–Rauscher reaction. Time history electrode potential was shown at saturation of environment with artificial aeration with oxygen in the reaction medium, the electro-magnetic radiation at frequencies of the absorption spectrum of oxygen environment, and the combined action of radiation and aeration.

Reference: 
  1. Briggs TS, Rauscher WC. An oscillating iodine clock. J. Chem. Educ. 1973;50(7):496–496.
  2. Jabotinsky AM, Ogmer X, Field RI. et al. Vibrations and traveling waves in chemical systems. Ed. Field R, Burger M. Moscow: Mir; 1988. 720 p. (In Russian).
  3. Budanov VG. Mesoparadigm of synergetics: Modeling of human-sized systems and the method of rhythm cascades. Synergetics. Workshop proceedings. Volume 4. Natural-scientific, social and humanitarian aspects. Moscow: MSU Press. 2001. 54–57 p. (In Russian).
  4. Ivanitskii GR, Medvinskii AB, Tsyganov MA. From the dynamics of population autowaves generated by living cells to neuroinformatics. Phys. Usp. 1994;37(10):961–989. DOI: 10.3367/UFNr.0164.199410b.1041.
  5. Andreev EA, Beliy MU, Sitko SP. Manifestation of the natural characteristic frequencies of the human body. Doklady of the Academy of Sciences of the Ukrainian SSR. 1984;10:56–59.
  6. Koltsov NK. Organization of the cell. Moscow-Leningrad: Biomedgiz; 1936. 652 p. (In Russian).
  7. Korzukhin MD, Zhabotinsky AM. Mathematical modeling of chemical and ecological self-oscillating systems. Oscillatory processes in biological and chemical systems. Ed. Frank GM. Мoscow: Nauka; 1967. 440 p. (In Russian).
  8. Graven SN, Estrada S, Lardy HA. Proc. Nat. Acad. Sci. U.S. 1965;53(5):1076–1083.
  9. Kovalenko AS, Tikhonova LP. Complex oscillatory regimes and their evolution in the Belousov-Zhabotinsky reaction. Zhurnal Fizicheskoi Khimii. 1989;63(1):71–73.
  10. Kovalenko AS, Tikhonova LP, Yatsimirskii KB. Effect of molecular oxygen on concentration autooscillations and autowaves in the Belousov-Zhabotinskii reaction. Theoretical and Experimental Chemistry. 1988;24(6):633–638. DOI: 10.1007/BF00531354.
  11. Furrow Stanley DA. Modified recipe and variations for the Briggs–Rauscher oscillating reaction. J. Chem. Education. 2012;89(11):1421–1424. DOI: 10.1021/ed200764r.
  12. Muntean N, Baldea I, Szabo G. et all. Antioxidant capacity determination by the Briggs–Rauscher oscillating reaction in a flow system. An application of functional dynamics in analytical chemistry. Studia Universitatis Babes–Bolyai Chemia. 2010;55(1):121–132.
  13. Basch R, Seiders M. An investigation of the Briggs–Rauscher reaction. Milestone 5. 2003;21:512–513.
  14. Kiselev MA, Rodents YA, Dobretsov GE, Komarova MN. The size of human serum albumin molecules in solution. Biofizika. 2001;46(3):423–427.
  15. Goldstein BN, Aksirov AM, Zakrjevskaya DT. A simple kinetic model for dynein oscillatory activity. Molecular Biology. 2008;42(1):123–126. DOI: 10.1007/s11008-008-1018-2.
  16. Usanov DA, Rytik AP. Influence of terahertz electromagnetic radiation on the frequency of absorption of molecular oxygen on Briggs–Rauscher oscillating reaction. Izvestiya VUZ. Applied Nonlinear Dynamics. 2012;20(5):44–50. DOI: 10.18500/0869-6632-2012-20-5-44-50.
  17. Plambek D. Electrochemical methods of analysis. Мoscow: Mir; 1985. 504 p. (In Russian).
  18. Melikhov DP, Vanag VK. Study of possible macromixing effects in photoinduced phase transitions in the Briggs–Rauscher reaction under batch conditions. Russian Journal of Physical Chemistry. 1995;11:2064.
Received: 
20.03.2013
Accepted: 
26.06.2013
Published: 
31.12.2013
Short text (in English):
(downloads: 69)